1-(3-Chlorophenyl)-3-(2,6-dichlorobenzoyl)thiourea
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چکیده
The structure of the title compound, C(14)H(9)Cl(3)N(2)OS, is composed of discrete mol-ecules with bond lengths and angles quite typical for thio-urea compounds of this class. The plane containing the thio-carbonyl and carbonyl groups subtends dihedral angles of 48.19 (3) and 87.51 (3)° with the planes formed by the 3-chloro and 2,6-dichloro-phenyl rings, respectively; the dihedral angle between the two benzene ring planes is 45.32 (3)°. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation and the mol-ecules form inter-molecular N-H⋯S and N-H⋯O hydrogen bonds, generating a sheet along the a axis.
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1-(4-Chlorophenyl)-3-(2,4-dichlorobenzoyl)thiourea
The title compound, C(14)H(9)Cl(3)N(2)OS, has bond lengths and angles which are quite typical for thio-urea compounds of this class. The mol-ecule exists in the solid state in its thione form with typical thio-urea C=S and C=O bond lengths, as well as shortened C-N bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. Inter-molecular N-H⋯S hydrogen bonds link the...
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